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****Leaving Certificate Chemistry [All Levels] Before and After Discussion****

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  • Closed Accounts Posts: 913 ✭✭✭MacBizzle


    booblefoop wrote: »
    Is it that it had been made up to a solution of known concentration? That was a weird one, they usually ask what a primary standard is :/

    Yeah that's it :)


  • Registered Users Posts: 99 ✭✭Yulkmn


    anyone know for the rates if u put the time on the bottom and temperature on the side if that's okey ??


  • Registered Users Posts: 56 ✭✭mirrors


    Yulkmn wrote: »
    anyone know for the rates if u put the time on the bottom and temperature on the side if that's okey ??
    No I'd say you'd lose a few marks
    booblefoop wrote: »
    Is it that it had been made up to a solution of known concentration? That was a weird one, they usually ask what a primary standard is :/

    A solution with a known concentration


  • Closed Accounts Posts: 913 ✭✭✭MacBizzle


    Yulkmn wrote: »
    anyone know for the rates if u put the time on the bottom and temperature on the side if that's okey ??

    Wasn't it rate not time?


  • Registered Users Posts: 99 ✭✭Yulkmn


    MacBizzle wrote: »
    Wasn't it rate not time?

    it was 1/t
    I put it on the x axis and put temperature on the y axis


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  • Closed Accounts Posts: 913 ✭✭✭MacBizzle


    Yulkmn wrote: »
    it was 1/t
    I put it on the x axis and put temperature on the y axis

    I think that's the right way, well that's what everyone in my class did. I did it the other way though and am nearly sure it's wrong :rolleyes:


  • Registered Users Posts: 82 ✭✭TooMuchStudy


    MacBizzle wrote: »
    I think that's the right way, well that's what everyone in my class did. I did it the other way though and am nearly sure it's wrong :rolleyes:

    is it not the value you set on the x-axis and the variable on the y-axis?


  • Registered Users Posts: 2,906 ✭✭✭Peter Flynt


    Everytime the world cup is on . . Soap appears - 2002, 2006, 2010, 2014. .


  • Registered Users Posts: 99 ✭✭Yulkmn


    is it not the value you set on the x-axis and the variable on the y-axis?

    yeah the variable is the temp isn't it?
    and did u get something like 66 seconds for the next part?


  • Registered Users Posts: 29,509 ✭✭✭✭randylonghorn


    Everytime the world cup is on . . Soap appears - 2002, 2006, 2010, 2014. .
    And in real life it's usually a conflict between the World Cup and the soaps in a lot of houses ... :pac:


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  • Closed Accounts Posts: 913 ✭✭✭MacBizzle


    Yulkmn wrote: »
    yeah the variable is the temp isn't it?
    and did u get something like 66 seconds for the next part?

    Did your graph start off steep and then get less steep or did it get steeper as it went on?


  • Registered Users Posts: 98 ✭✭Apocladagr0


    What was the proper definition for standardised too, actually?

    And what did people say for butane/propane differences? I said higher molecular mass and stronger Van der Waals forces for butane, was that right?

    For standardised I said ' a soln. of precisely known concentration '.
    I vaguely remember being told to be more detailed in a class test for that question but I couldn't remember what else to write:rolleyes:

    I said more v.d.w. for butane too. I knew it was a six marker so they would probably be expecting two points but I couldn't think of another:o

    Also for equilirium my x came out to be 0.9
    So the #mol N2 at equil = 2-2x = 0.2 mol. ??


  • Registered Users Posts: 6,818 ✭✭✭Inspector Coptoor


    A very rough sketch of Q3
    And the graph of rate vs temp.



    For the butane vs propane question.
    Id be saying higher Mr means more bonds meaning increased vdw forces which raises the bp


  • Closed Accounts Posts: 913 ✭✭✭MacBizzle


    And the graph of rate vs temp.

    That's the right way!?! :D


  • Closed Accounts Posts: 175 ✭✭brian888


    MacBizzle wrote: »
    That's the right way!?! :D

    could've fcuking sworn it was the opposite way round on the axes. Ah well, I only need a D3 anyways!


  • Registered Users Posts: 99 ✭✭Yulkmn


    MacBizzle wrote: »
    That's the right way!?! :D

    I put it as 1/t to be x-axis and it came out different like it went upwards from xaxis and kinda to the right in a curve

    like I don't think you would lose a lot of marks if u did it the other way, cause it only said time vs temp


  • Registered Users Posts: 2,906 ✭✭✭Peter Flynt


    Since you're on the topic. . .

    ScreenShot2014-06-17at225140_zps37726551.png


  • Closed Accounts Posts: 175 ✭✭brian888


    You sir, make me sad. :D


  • Registered Users Posts: 99 ✭✭Yulkmn


    Since you're on the topic. . .



    can you make one with the axis' switched around?


  • Registered Users Posts: 6,818 ✭✭✭Inspector Coptoor


    You could.
    But it would be wrong


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  • Registered Users Posts: 99 ✭✭Yulkmn


    You could.
    But it would be wrong

    how tho? it just switching the axises


  • Registered Users Posts: 15,382 ✭✭✭✭rainbowtrout


    EoghanIRL wrote: »
    Could you do the equilibrium calculation and see what answer you get . It would be great if you had time . I haven't seen the answer anywhere on here yet .



    Chem equilibrium Q9


  • Registered Users Posts: 6,818 ✭✭✭Inspector Coptoor


    It would change the shape of the graph and tell an examiner the candidate didnt know a dependent variable from an independent variable


  • Registered Users Posts: 2,906 ✭✭✭Peter Flynt


    If you got the axes the wrong way around . . . Don't panic

    In 2002 for the same experiment (although with rate against concentration rather than temperature) it stated this directly from the marking scheme.

    ScreenShot2014-06-17at225859_zps85327128.png

    See it there. . . "Rate can be on horizontal or vertical axis; similarly for concentration"


  • Registered Users Posts: 6,818 ✭✭✭Inspector Coptoor


    Talk about hand holding.
    Who's doing the exam?
    The candidates or the examiners?

    That's like saying 2 + 2 = 4
    Or 5


  • Registered Users Posts: 99 ✭✭Yulkmn


    If you got the axes the wrong way around . . . Don't panic

    In 2002 for the same experiment (although with rate against concentration rather than temperature) it stated this directly from the marking scheme.]

    See it there. . . "Rate can be on horizontal or vertical axis; similarly for concentration"

    thank you pheeeew :D do you know if there's attempt marks for the questions such as the equillbrium and the last part in Q1 the finding the value X ??


  • Registered Users Posts: 57 ✭✭yoajing


    Isn't brine needed to precipitate the soap?


  • Registered Users Posts: 98 ✭✭Apocladagr0


    Chem equilibrium Q9

    Don't you have to do 2-2x though, so final answer is 0.2 mol. ?


  • Registered Users Posts: 15,382 ✭✭✭✭rainbowtrout


    Don't you have to do 2-2x though, so final answer is 0.2 mol. ?

    The question asks how many moles of nitrogen gas so 0.9 moles.

    But it would be 0.2 moles if it asked for how many moles of NO at equilibrium


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  • Registered Users Posts: 99 ✭✭Yulkmn


    Don't you have to do 2-2x though, so final answer is 0.2 mol. ?

    you'll still get nearly full marks.
    I did :
    at equilibrium 2x = 1-x 1-x
    then put it in and equaled it to 21 ( or what ever the kc was)
    then I went on and did the -b formula
    and got x to be 0.025 and 47 I disregarded the 47 and took the 0.025 and got 1-0.025 and which is .975.
    anybody think I'll get any marks for that?


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